Vol. 44, Issue 21
October 17, 2005 Cover
The novel 3-Sb2S4 ligand in (C5Me5)3Rh3
Sb2S5 contains a stable terminal Sb=S double bond. The electron density gradient
and bond critical points obtained by DFT calculations for the model compound H2Sb(SH)=S are shown in the background. The title compound has been obtained from Sb2S3 (antimonite), K, and S8 via K3SbS3
and (C5Me5)2Rh2Cl4. See A. Lange, M. M. Kubicki, J. Wachter, and M. Zabel, p 7328.