The research training group GRK 1626 develops selective chemical photocatalysts for endothermic or kinetically hindered organic reactions and describes the key parameters of their design and function. This will pave the way to a broader use of solar energy for chemical transformations.
The photocatalysts consist of a redox active chromophore (sensitizer) and a catalytic unit or substrate binding site. Irradiation with light induces a charge separation between the electron donor and the electron acceptor unit of the photocatalyst, which is coupled to a subsequent chemical reaction. The charge separation may occur within the photocatalyst or between the photocatalyst and a bound substrate. The absorbed light energy contributes to the overall energy balance of the reaction and is thereby transformed into chemically stored energy or substitutes reagents, which are otherwise necessary to achieve conversion.
Although the physical primary steps of a photocatalysis are considered to be well understood, a description of electron transfer is provided by the Marcus-theory and mechanisms of catalysis are thoroughly investigated, a rational design of efficient photocatalysts is still very difficult: To achieve an effective photocatalysis the exact kinetic, energetic and geometric coupling of electronic and chemical steps is necessary. A more thorough investigation of the parameters describing these interdependencies is the goal of the planned research training group.
Catalyses involving one electron transfer processes, such as radical cyclizations, or two electron transfer processes, e.g. two coupled redox transformations, will be investigated in interdisciplinary research projects. Whenever possible, the visible part of the solar light spectrum will be used as energy source. The structures of the photocatalysts are systematically varied and thermodynamic and kinetic key parameters are determined.
We expect from the detailed spectroscopic analysis and theoretical description of the photoreactions a better understanding of the important and general parameters describing an effective coupling of primary photo processes and subsequent chemical reactions.
The research training group provides PhD students an excellent environment for inter-disciplinary research in this forward looking research area.